Solving a puzzling problem of condensed matter physics using inelastic spectroscopy
Spectroscopic investigations are essential to understand intriguing phenomena in many areas of physics. In particular, recent advanced spectroscopic tools such as resonant inelastic x-ray scattering and photoemission spectroscopy play an important role in condensed matter physics. While research on thin-films or superlattices is expected to reveal hidden novel physical properties, previous inelastic spectroscopic investigations have been unable to detect these properties due to the small cross-section.
In this colloquium, I will discuss advanced inelastic light scattering (Raman spectroscopic) studies of two-magnon dynamics in Sr2IrO4 thin-films as functions of strain and temperature. Recent experimental studies of Sr2IrO4 thin-films have contradicted the widely-accepted Glazer description of octahedral tilting and rotation in perovskite oxides. However, our experimental observations and density functional theory calculations show that the multi-orbital nature of the Jeff = ½ state is crucial to understanding the magnetic and electronic properties of 5d transition-metal oxides. This study demonstrates how advanced spectroscopic tools improve our fundamental understanding of strongly correlated, spin-orbit coupled electrons, enabling us to explore the novel phase diagrams of these systems.